Alken® Treatment J-674 - MATERIAL SAFETY DATA SHEET

ALKEN® TREATMENT J-674

Effective Date: 04/04/2007

Material Safety Data Sheet
Manufacturer's Name: Alken-Murray Corporation
Manufacturer's Address: P.O. Box 400, New Hyde Park, New York 11040
	T: 540-636-1236 Fax: 540-636-1770
	E-mail: msds@alken-murray.com
Manufacturer's Cage Code: 2A384
For chemical emergency - spill, leak, fire or accident - call CHEMTREC - day or night - (800) 424-9300 in North America - For foreign emergencies -(703) 527-3887 collect calls accepted.

HMIS & NFPA Hazard Ratings:

0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe

Health=2

Fire=2

Reactivity=0

Hazard Symbol: C

Canadian WHMIS Classification E

All ingredients on Canadian DSL and USA TSCA lists

1. Product Identification

Synonyms:	Oxygen Scavenging Condensate Corrosion Inhibitor
CAS Number:	Not applicable to mixtures
Chemical Formula:	Proprietary Mixture
Formula ID Codes:	674

2. Composition/Information on Ingredients

Chemical Name	CAS Number	OSHA PEL	ACGIH TLV	% Weight
Water	7732-18-5	NDA	NDA	80 - 98
N,N-Diethylethanolamine (DEAE)	100-37-8	NDA	2 ppm TWA	1 - 10
Cyclohexlamine	108-91-8	NDA	10 ppm TWA	1 - 10

Ingredients not precisely identified are proprietary and/or non-hazardous. All chemical ingredients appear on the EPA TSCA inventory.

3. Hazards Identification

Emergency Overview: DANGER! Corrosive. Toxic. Danger of explosion. Harmful if swallowed. Irritating to eyes and skin burns. Causes digestive and respiratoryy tract burns. Hygroscopic. Target organs: Blood, central nervous system

Potential Health Effects:

Signs and Symptoms of Acute Overexposure: Irritating to eyes, skin, respiratoruy tract and digestive system.
Signs and Symptoms of Chronic overexposure: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
Medical Conditions Generally Aggravated by Exposure: None known.

4. First Aid Measures

Inhalation: Remove victim to fresh air. Get prompt medical attention.
Ingestion: Do not induce vomiting. Allow victim to rinse mouth with and then drink 2 - 4 cupfuls of water. Get victim to hospital promptly.
Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse. Get medical attention if skin is burned or if irritation persists.
Eye Contact: Immediately flush eyes with water for 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical attention.
Note to Physician: Treat symptomatically and supportively. There is no specific antidote.

5. Fire Fighting Measures

Flash Point: 165 degrees F (73.9 degrees C)

Flammability Limits: NDA

Autoignition temp: NDA

Fire Extinguishing Media: Water spray, dry chemical, chemical foam or alcohol-reistant foam

Special Fire-Fighting Information: Wear NIOSH-approved SCNA. Use water spray to cool containers and to knock down fumes.

Unusual Fire and Explosion Hazards: Noxious amine vapor may be released.

6. Accidental Release Measures

Use proper personal protection apparatus and appropriate breathing apparatus as indicated in Section 8. Dike spillage, scoop up with absorbent material and place in containers. A vapor suppressing foam may be used to reduce vapors.

7. Handling and Storage

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Store in cool dry place away from incompatible substances. Keep container closed when not in use. Store at moderate temperatures, do not freeze. Avoid contact with liquid, mists or dried residues. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flame. Follow disposal instructions for hazardous chemical waste. Do not ingest or inhale.

**8. Exposure Controls/ Personal Protection**
Ventilation System: Good general ventilation is advisable. Local exhaust ventilation to decrease airborne concentration below permissible exposure limits. Personal Respirators (NIOSH or EN 149 Approved): Wear an approved self-contained unit with full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Skin Protection: Rubber gloves, boots and apron. Body covering clothing Eye Protection: Chemical safety goggles, full face shield Other Control Measures: None Exposure Limits: ACGIH: CAS #100-37-8: 2 ppm; 9.6 mg/m3; skin - potential cutaneous absorption CAS#108-91-8: 10 ppm; 41 mg/m3 NIOSH: CAS #100-37-8: 10 ppm TWA; 50 mg/m3 TWA 100 ppm IDLH CAS# 108-91-8: 10 ppm TWA; 40 mg/m3 TWA OSHA - Final PELs:10 ppm TWA; 50 mg/m3 TWA; Vacated PELs: CAS# 100-37-8: 10 ppm TWA; 50 mg/m3 TWA CAS # 108-91-8: 10 ppm TWA; 40 mg/m3 TWA

9. Physical and Chemical Properties

Appearance and Color: Colorless or pale yellow liquid.
Odor: Sharp fish-amine odor
Solubility in Water: Miscible
Specific Gravity: 0.99
pH: 12.7
% volatile by volume @ 21C (70F): NDA
Boiling Point: 212 degrees F
Melting Point: NDA
Vapor Density (Air=1): NDA
Vapor Pressure (mm Hg): NDA
Evaporation Rate (Bu. Acetate=1): =Water

10. Stability and Reactivity

Stability: Product is stable.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia and/or derivatives
Hazardous Polymerization: has not been reported.
Incompatibility: : Copper, brass, aluminum, acids, oxidizing agents, chlorine, hypochlorite, nitric acid
Conditions to Avoid: Incompatibile chemicals, ignition sources, excess heat.

**11. Toxicological Information**
Toxicological Data: RTECS:CAS# 7732-18-5: ZC0110000 / CAS# 100-37-8: KK5075000 / CAS# 108-91-8:GX07000000 / LD/LC50:CAS# 7732-18-5: LD50= >90 mL/Kg / CAS# 100-37-8: Oral, rat LD50 = 1300 mg/Kg / CAS# 108-91-8: Oral, rat LD50 = 7500 mg/Kg Carcinogenicity: ACGIH-A4: Cyclohexylamine, "suspected animal carcinogen", but NOT rated as carcinogen by IARC,NIOSH, NTP or OSHA. Other ingredients are NOT found on any lists published by ACGIH, IARC, NIOSH, NTP or OSHA

12. Ecological Information

Environmental Fate: This material is not expected to significantly bioaccumulate. When released into the soil, Cyclohexylamine may biodegrade and may evaporate, to a moderate extent. When released into the soil, this material may leach into groundwater. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals.

Environmental Toxicity: NDA

**13. Disposal Considerations**
RCRA Hazard Class (if discarded): CORROSIVE D001 & D002 Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. . As a hazardous liquid, this product should be solidified with stabilizing agents (such as sand, cement or fly ash), so that no liquid remains, before disposal to a licensed, industrial waste landfill (Hazardous Waste Treatment Storage and Disposal Facility). A hazardous liquid waste can also be incinerated, in accordance with local, state and federal regulations. Empty containers may contain residues. Thoroughly clean empty container, then offer for recycling, reuse or disposal in accordance with federal, state and local requirements.

14. Transportation Information

DOT Proper Shipping Name: Corrosive liquid, NOS, UN 1760
DOT Hazard Class: (8)
UN Number: 1760
Packing Group: II
DOT Label: Corrosive liquid, N.O.S (contains amines) Class 8, UN 1760, PG II

15. Regulatory Information

TSCA: (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
CERCLA Reportable Quantity: 1 lb. of cyclohexylamine (approx. 2 gal. of product)

SARA TITLE III:

Section 302/304 Extremely Hazardous Substances: Cyclohexylamine, CAS 108-91-8: TPQ = 10,000 pounds; RQ = 40,000 lbs (does not meet toxicity criteria, but because of high production volume and recognized toxicity is considered a chemical of concern)

Section 311 Hazard Categorization: Acute, Chronic, Flammable

Section 313 Toxic Chemicals: None

Clean Water Act: This product contains no ingredients that CWA lists on its "Hazardous Substances", "Priority Pollutant" or "Toxic Pollutant" lists.
Clean Air Act: Cyclohexylamine, CAS# 108-91-8 IS listed as a hazardous air pollutant (HAP) by CAA, section 111. This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
OSHA: None of the chemicals in this formula are considered highly hazardous.
FDA: This product complies with 21 CFR 184.1139 regulations for boiler water additives used in preparation of steam that will contact food.
USDA: This product is authorized for use in federally inspected meat and poultry plant
STATE RIGHT-TO-KNOW LISTS: Cyclohexylamine, CAS# 108-91-8, representing 7.1% of this product, and N,N'-Diethylethanolamine (DEAE), CAS 100-37-8 representing 9% of this product ARE found on the following RTK lists: California, New Jersey, Florida, Pennsylvania, Minnesota & Massachusetts. Other ingredients NOT listed on the following RTK lists: California, Florida, Illinois, Louisiana, Maine, Maryland, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island. or Tennessee.
Not subject to California Proposition 65 Labeling
WGK (Water Danger/Protection): CAS # 100-37-8: 1 /CAS 108-91-8: 1
Canada CAS # 100-37-8 & 108-91-8 are listed on Canada's DSL/NDSL list and is not listed on their disclosure list.
WHMIS classification: NDA.
Canada's Ingredient Disclosure List: N,N'-Diethylethanolamine, (DEAE) CAS 100-37-8, comprising 9% of this product and Cyclohexylamine, CAS 108-91-8, comprising 7.1% of this product IS listed on the CIDL, but other ingredients are "NOT CONTROLLED". This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

Reason for Revision: Routine Review and Revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.

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