Effective Date: 06/16/2008

 Product Bulletin

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 Material Safety Data Sheet
 Manufacturer's Name: Alken-Murray Corporation
 Manufacturer's Address: P.O. Box 400, New Hyde Park, New York 11040
  T: 540-636-1236 Fax: 540-636-1770
 Manufacturer's Cage Code: 2A384
For chemical emergency - spill, leak, fire or accident - call CHEMTREC - day or night - (800) 424-9300 or outside the USA (703) 527-3887

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NFPA Hazard Ratings:

0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe

 Health=2  Fire=0  Reactivity=0


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Canadian WHMIS Classification E & D2B

All ingredients on Canadian DSL and USA TSCA lists 

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1. Product Identification

 Synonyms: Liquid Inhibited Amidosulfamic Acid Cleaner , Liquid Inhibited Amidosulfuric Acid Cleaner, Liquid Inhibited Sulfamic Acid Cleaner
 CAS Number:  Not applicable to mixtures
 Chemical Formula:  mixture
 Formula ID Codes:  0893

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2. Composition/Information on Ingredients

 Chemical Name  CAS Number  OSHA PEL   ACGIH TLV   % Weight
 Water  7732-18-5  NDA  NDA 80 - 90
 Sulfamic acid  5329-14-6  NDA  NDA 10 - 20
 Hexamine  100-97-0  NDA  NDA  < 1
 Calcium chloride  10043-52-4  NDA NDA  < 1
 Propylene glycol  57-55-6  NDA  NDA  < 1
 Phosphoric acid  7664-38-2  NDA   NDA  < 1
 Isopropyl alcohol  67-63-0  NDA  NDA  < 1
Propargyl alcohol  107-19-7  NDA  NDA  < 1
 DuPont Zonyl FSN Fluorosurfactant  * 65545-80-4  NDA  NDA   < 1

*New Jersey Trade Secret # 00850201001-5285P (Telomer B monoether with PEG)

Ingredients not precisely identified are proprietary and/or non-hazardous per 29 CFR 1910-1200 and/or represent less than 1%... All chemical ingredients appear on the EPA TSCA inventory.



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3. Hazards Identification

Emergency Overview: CAUTION: May cause severe irritation to eyes. May be irritating to respiratory tract. May be fatal if swallowed.

Potential Health Effects:

  • Signs and Symptoms of Acute Overexposure: Contact with mist, or vapor may cause skin irritation. Contact with eyes will cause immediate pain. May be corrosive to corneal tissue. May cause irritation to nose and throat. May be corrosive to esophagal linings and mucous membranes if ingested.
  • Signs and Symptoms of Chronic overexposure: Repeated exposure may cause chronic bronchitis or respiratory inflammation. Repeated or extended skin contact may be corrosive. Repeated eye contact may cause conjunctivitis and photosensitization
  • Medical Conditions Generally Aggravated by Exposure: NDA
  • Other Comments: NDA

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4. First Aid Measures

  • Inhalation: Remove patient to fresh air. Get prompt medical attention
  • Ingestion: Do not induce vomiting. Give patient large amounts of milk or water to drink. Get patient to hospital promptly.
  • Skin Contact: Remove contaminated clothing and footwear. Wash skin for 15 minutes with soap and water. Wash clothing before reuse. If irritation persists, get medical attention.
  • Eye Contact: Immediately flush eyes with water for 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye and eyelid tissue. Do not allow patient to rub or keep eyes closed. Get immediate medical attention.
  • Note to Physician: Treat symptomatically. No specific antidote.

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5. Fire Fighting Measures

Flash Point: None

Flammability Limits: NDA

Autoignition temp: NDA

Fire Extinguishing Media: Not combustible. Suitable for surrounding fire.

Special Fire-Fighting Information: Wear NIOSH-approved SCNA. Use water spray to cool containers.

Unusual Fire and Explosion Hazards: Sulfur dioxide, sulfur trioxide and ammonia gases may be released in fire, if water is allowed to evaporate.Wear SCNA if in fire situation.

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6. Accidental Release Measures

Avoid skin contact. Contain spill in order to prevent contamination of sewage system or water way. Pump into marked containers for reclamation or disposal. Absorb spill with inert material, (e.g., dry sand, vermiculite or earth), then place in a chemical waste container. If possible, neutralize residue on a dry basis with suitable alkali, such as lime or soda ash; then flush with water in accordance with applicable regulations. Flush neutralized residues to sanitary sewer with water.

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7. Handling and Storage

Store in cool dry place. Store in a tightly closed container. Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with skin, eyes, and clothing. Do not inhale or ingest.

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8. Exposure Controls/ Personal Protection

  • Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
  • Personal Respirators (NIOSH Approved): Use approved full-face respirator, optional. Consult respirator manufacturer to determine appropriate equipment. Warning: Air purifying respirators do not protect employees in oxygen limited environments.
  • Skin Protection: Rubber gloves, boots and apron. Body covering clothing to minimize exposure
  • Eye Protection: Splash-proof chemical safety goggles, full face shield. Do not wear contact lenses. Recommend eyewash fountain nearby where product is handled in concentrated form
  • Other Control Measures: A source of clean water should be available in the work area or flushing eyes and skin.
ACGIH: CAS 5329-14-6: 1 mg/m3
OSHA Vacated PELs: NDA

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9. Physical and Chemical Properties

  • Appearance and Color: Transparent light pink water-thin liquid
  • Odor: Amine odor
  • Solubility in Water: 100%
  • Specific Gravity: 1.073
  • pH: 1.3 (acidic)
  • % volatile by volume @ 21C (70F): 85% weight by volume
  • Boiling Point: 215 degrees F (102 degrees C)
  • Freezing Point: 30 degrees F (-1 degrees C)
  • Melting Point: NDA
  • Vapor Density (Air=1): = 100 C (212 F)
  • Vapor Pressure (mm Hg): = water
  • Evaporation Rate (Bu. Acetate=1): = < 1

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10. Stability and Reactivity

  • Stability: Product is stable under normal conditions of storage and handling. In water solution, slowly hydrolyzes to form ammonium sulfate and bisulfate.
  • Hazardous Decomposition Products: Sulphur dioxide and sulphur trioxide gases, nitrogen oxides, ammonia in a fire, if water content is allowed to evaporate
  • Hazardous Polymerization: will not occur.
  • Incompatibility: Strong oxidizers, nitric acid, chlorine. Solution is acidic and reacts violently with bases.
  • Conditions to Avoid: Incompatible substances

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11. Toxicological Information

  • Toxicological Data: (CFR Title 16)
RTECS: CAS# 5329-14-6: WO5950000/ CAS 7732-18-5: ZC0110000/ CAS# 100-97-0: MN4725000/ CAS# 10043-52-4:EV9810000/ 100-97-0: MN4725000/ CAS# 57-55-6: TY2000000 / CAS# 7664-38-2: TB6300000/ CAS# 67-63-0: NT8050000 / CAS# 65545-80-4:TR1581533 / CAS# 107-19-7: UK5075000

LD50 /LC50: CAS# 7732-18-5: LD50= >90 mL/Kg / CAS# 5329-14-6: Oral, mouse = 1312 mg/Kg; oral rat = 3160 mg/Kg, Dermal rabbit: 500 mg/24H SEVERE, / CAS# 100-90-0: Oral, mouse LD50 = 569 mg/kg / CAS# 10043-52-4: Oral, mouse LD50 = 1940 mg/Kg; Oral, rat LD50 = 1 g/Kg / CAS# 57-55-6: Oral, rat LD50 = 20 g/Kg / CAS# 7664-38-2: Oral, mouse LD50 = 1.25 g/Kg; Oral, rat LD50 = 1530 mg/Kg / CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit = 12800 mg/kg / CAS# 65545-80-4: Oral, mouse LD50 = 1700 mg/Kg / CAS# 107-19-7: Oral, rat LD50 = 20 mg/Kg; Oral, mouse LD50 = 50 mg/Kg
  • Carcinogenicity:
IARC: Isopropyl alcohol are Group 3 animal carcinogen, but NOT listed on ACGIH, NIOSH, NTR or OSHA.
Other Ingredients are not listed as carcinogens by ACGIH, IARC, NIOSH, NTR, or OSHA

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12. Ecological Information

  • Environmental Fate: NDA
  • Ecotoxicity: NDA
  • Environmental Toxicity: Can cause a serious pH drop if not thoroughly diluted or neutralized prior to dispensing into sewer system or other body of water.

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13. Disposal Considerations

 RCRA Hazard Class (if discarded): CORROSIVE D002 Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. State and local disposal regulations may differ from federal disposal regulations. Empty containers may contain residues. Thoroughly clean empty container, then offer for recycling, reuse or disposal in accordance with federal, state and local requirements.

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14. Transportation Information (49 CFR 172.101)

  • DOT Proper Shipping Name: Sulfamic acid solution, Class 8, UN 2967, PG III
  • UN/NA ID Number: 2967
  • Packing Group: III
  • DOT Label: Corrosive Liquid, N.O. S. (Contains Sulfamic acid, solution) Class 8, UN 1760, PG II
  • TDG CLASSIFICATION: Corrosive material, Class 8

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15. Regulatory Information

  • TSCA: (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
  • CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302

..................................Section 302/304 Extremely Hazardous Substances: None of the ingredients have a TPQ

..................................Section 311 Hazard Categorization: Acute Health, Delayed Health, Chronic Health

..................................Section 313 Toxic Chemicals: Not listed

  • Clean Air Act: This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
  • Clean Water Act: None of the chemicals in this formula are listed as Priority Pollutants or hazardous substances under CWA.
  • OSHA: Hazardous by definition of Hazard Communication Standard (29CFR 1910.1200)
  • STATE RIGHT-TO-KNOW LISTS: Sulfamic acid, CAS#5329-14-6 (15%) IS listed on the following RTK lists: California, Connecticut, Florida, Illinois, Louisiana, Massachusetts, Maine, Minnesota, New Jersey, Pennsylvania, & Rhode Island. CAS# 100-97-0, Hexamine (<1%) IS listed on the following RTK list: New Jersey. CAS# 67-63-0, Isopropyl alcohol (< 1%) is listed on the following RTK lists:California, New Jersey, Florida, Pennsylvania, Minnesota & Massachusetts. CAS# 107-19-7, Propargyl alcohol (<1%) IS found on the following RTK lists: Florida, Massachusetts, Minnesota, New Jersey, New York, Rhode Island, & Tennessee. Other ingredients are NOT listed on the following RTK lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Maryland, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island or Tennessee.
  • Not subject to California Proposition 65 labeling requirements (California)
  • Canadian DSL: All ingredients are listed on the Canadian DSL. Product is approved for sale in Canada.
  • Canada's Ingredient Disclosure List: Sulfamic acid, CAS# 5329-14-6, representing 15% of this product, Hexamine, CAS# 100-97-0, representing < 1% of this product and Propargyl alcohol, CAS# 107-19-7 representing <1% of this product ARE listed on the CIDL but other ingredients are not found on that list. This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
  • Canadian WHMIS: "Class E" (Corrosive) Class D2B "Other Toxic Effects"
  • IMDG: Corrosive Liquid, N.O. S. (Sulfamic acid, solution) Class 8, UN 2967, PG III
  • IATA: Corrosive Liquid, N.O. S. (Sulfamic acid, solution) Class 8, UN 2967, PG III
  • EmS Code: F-A, S-B
  • Packing Instructions: P001, LP01
  • IBC Instructions: IBC03
  • IMO Tank Instructions: T4
  • UN Tank Instructions: T7
  • European Labeling in Accordance with EC Directives EINECS# 226-218-8. Hazard Symbols: XI
    Risk Phrases: R35 - causes severe burns, R43 - may cause skin sensitization by skin contact
    Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident of if you feel unwell, seek medical advice immediately (show the label where possible). S 9 Keep container in a well-ventilated place.
  • Other Countries: CAS# 5329-14-6 is also listed on the chemical inventory in the following countries: EC, Japan, Australia, Korea, DSL, NDSL, Philippines. Australia Haz Chem Code: 2T; Poison Schedule: S6;
  • Austrailian HazChem Code: 2T, Poison Schedule: S6

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16. Other Information

Reason for Revision: Section 6 Revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.

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