NFPA Hazard Ratings:

•  Manganese 2-Ethylhexanoate

• Manganese Neodecanoate

• Manganese Stearate

Emergency Overview: Caution: Eye and respiratory irritant. Manganese compounds can cause central nervous system and pulmonary system damage by inhalation of fumes and dust. Manganese is a known skin and eye irritant. Alken 935 may be harmful if swallowed. Wash hands thoroughly after handling.

Potential Health Effects:

• Signs and Symptoms of Acute Overexposure: Eye, respiratory irritation, dizziness, fatigue, headache, unconsciousness or asphyxiation.
• Signs and Symptoms of Chronic overexposure: Dermatitis and defatting of skin
• Medical Conditions Generally Aggravated by Exposure: Allergies, chronic asthma may be exacerbated by fumes from this product..
• Ingestion: Irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion.

• Inhalation: Remove victim to fresh air. If breathing is impaired, administer oxygen. Keep patient warm and quie.t
• Ingestion: Do not induce vomiting. Give patient 2 - 4 glasses of water or milk to drink to dilute the product. Get medical advice.
• Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
• Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
• Note to Physician: None

 Flash Point: 160 degrees F

Flammability Limits: NDA

Autoignition temp: NDA

Fire Extinguishing Media: Foam, water fog, carbon dioxide, dry chemical

Special Fire-Fighting Information: Wear NIOSH-approved SCNAone. Use water spray to ool containers.

Unusual Fire and Explosion Hazards: Vapors are heavier than air and may travel along the ground.

• Ventilation System: Good general ventilation is advisable
• Personal Respirators (NIOSH Approved): if needed, use respirator to screen out nuisance dust
• Skin Protection: Long sleeved clothing and oil-resistant gloves
• Eye Protection: Chemical safety goggles or face mask.
• Other Control Measures:

ACGIH (TVL) Limits:
CAS # 8032-32-4: 525 mg/M3, A3 - Animal carcinogen
CAS# 8012-95-1: 5 mg/M3
OSHA PEL: CAS# 64741-60-2: 2000 mg/M3
CAS# 8012-95-1: 5 mg/M3
Manganese carboxylates -5 mg/M3
OSHA - Class IIIA (combustible)

• Appearance and Color: Dark brown liquid.
• Odor: Aromatic odor
• Solubility in Water: Nil
• Specific Gravity: 1.0143 at 60 degrees F
• Density: 8.456 lb/gal
• Kinematic viscosity @ 100 deg. F: 3.45
• pH: NA
• % volatile by volume @ 21C (70F): NDA
• Boiling Point: 400 degrees F, 100 degrees C
• Melting Point: NA
• Vapor Density (Air=1): = > 1
• Vapor Pressure (mm Hg): = < 5
• Evaporation Rate (Bu. Acetate=1): = < 1

• Stability: Product is stable under normal conditions.
• Hazardous Decomposition Products: Carbon monixide and ioxide on combustion
• Hazardous Polymerization: will not occur.
• Incompatibility: Strong oxidizers. May soften some plastics.
• Conditions to Avoid: Incompatibilites.

• Toxicological Data:

RTECS: NDA
LD50 /LC50: CAS# 8032-32-4: Inhalation rat LC50: 3400 ppm/4H. Investigated as a reproductive effector
Similar composition middle distillates have been found to be weekly to moderately tumorigenic in mouse skin-painting bio-assays. It is suspected these tumors may be due in part to chromic skin irritation, resulting from continuous contact with the test substance. The IARC has concluded that light and intermediate middle distillates are group 3 substances, "not classifiable as to their carconogenicity to humans", based on inadequate human and inadequate animal evidence.

• Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTR, or OSHA

• Environmental Fate: CAS# 8032-32-4: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to readily biodegrade. When released to water, this material is expected to quickly evaporate. This material has an estimated bioconcentration factor (BCF) of less than 100. This material is not expected to significantly bioaccumulate. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half-life between 1 and 10 days. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition.
• Environmental Toxicity: NDA

• DOT Proper Shipping Name: Petroleum Products, n.o.s (combustible)
• DOT Hazard Class: 3, combustible
• Packing Group: III
• DOT Label: Petroleum Products, n.o.s, 3, UN 1268, PG III - E.R.G. #1268
• UN Number: 1268

• TSCA: All ingredients are listed on the TSCA inventory with no special reporting regulations.
• CERCLA Reportable Quantity: Not subject to CERCLA reporting
• SARA TITLE III:

Section 302/304 Extremely Hazardous Substances: This product does not contain more than 1% of any chemical substance on the SARA Extremely Hazardous Substances List

Section 311 Hazard Categorization: Acute health, chronic, delayed Health

Section 313 Toxic Chemicals: Manganese compounds <10%

Not subject to Proposition 65 labeling requirements in California. This product is not known to contain any chemicals known to the state of California to cause cancer or birth defects. However, we do not conduct routine analysis for all listed materials.

• STATE Right-To-Know Lists: Ingredients not listed on Pennsylvania, New Jersey, California, Massachusetts
• CLEAN WATER ACT/OIL POLLUTION ACT: Manganese compounds. This product is classified as an oil under Section 31 of the Water Act (40 CFR 110) and the Oil Pollution Act of 1990. Discharges or spills which produce a visible sheen on either surface water or waterways/sewers which lead to surface water, must be reported to the National Response Center at 800-424-8802.
• CANADA: Ingredients listed on the Non-Domestic Substances List.
  WHMIS classification:CAS# 61791-24-0: 028,E

16. Other Information

Reason for Revision: Revised formula

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.