NFPA Hazard Ratings:

Emergency Overview: Caution: Eye and respiratory irritant.

Potential Health Effects:

• Signs and Symptoms of Acute Overexposure: Eye, respiratory irritation, dizziness, fatigue, headache, unconsciousness or asphyxiation.
• Signs and Symptoms of Chronic overexposure: Dermatitis and defatting of skin
• Medical Conditions Generally Aggravated by Exposure: Allergies, chronic asthma may be exacerbated by fumes from this product..
• Ingestion: Irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion.

• Inhalation: Remove victim to fresh air. If breathing is impaired, administer oxygen. Keep patient warm and quie.t
• Ingestion: Do not induce vomiting. Give patient 2 - 4 glasses of water or milk to drink to dilute the product. Get medical advice.
• Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
• Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
• Note to Physician: None

 Flash Point: 205 degrees F (96 degrees C) (Cleveland Open Cup)

Flammability Limits: NA

Autoignition temp: NA

Fire Extinguishing Media: Foam, water fog, carbon dioxide, dry chemical

Special Fire-Fighting Information: Wear NIOSH-approved SCNAone. Use water spray to ool containers.

Unusual Fire and Explosion Hazards: Vapors are heavier than air and may travel along the ground.

Land Spill: Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without hazard. Recover for use if possible, or transfer to suitable container for disposal. Use absorbent to clean up. Prevent liquid from entering sewers, water sources, or low areas. Contain spilled liquid with sand or earth. Do not use combustible materials, such as sawdust, to absorb spill. Wash down spill area with soap and water. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.

Water Spill: Remove from surface by skimming or with suitable absorbents. If allowed by local authorities and environmental agencies, sinking and/or suitable dispersants may be used in confined waters. Recovered material may be biodegraded with Alken Clear-Flo® 7036, supplemented by Alken® Bio-Nutrient 3 and Alken Clear-Flor® 5100, if a suitable aerated, treatment tank is available on-site. Consult your Alken-Murray distributor for more information.

• Ventilation System: Good general ventilation is advisable
• Personal Respirators (NIOSH Approved): if needed, use respirator to screen out nuisance dust
• Skin Protection: Long sleeved clothing and oil-resistant gloves
• Eye Protection: Chemical safety goggles or face mask.
• Other Control Measures:

ACGIH: CAS# 67-63-0: 400 ppm; 500 ppm STEL, CAS 64742-94-5: 100 ppm; CAS 91-20-3: 79 mg/M3

OSHA PEL: PEL:CAS # 67-63-0: 400 ppm CAS 64742-94-5: 100 ppm; CAS 91-20-3: 79 mg/M3

• Appearance and Color: Transparent amber liquid.
• Odor: Hydrocarbon odor
• Solubility in Water: Nil
• Specific Gravity: 1.002 at 60 degrees F
• Density - lb/gal: 8.35
• Viscosity at 40 deg.C: 4.88 cP
• pH: NA
• % volatile by volume @ 21C (70F): NDA
• Boiling Point: >228 degrees C, > 442 degrees F
• Melting Point: NDA
• Vapor Density (Air=1): = > 1
• Vapor Pressure (mm Hg): = < 5
• Evaporation Rate (Bu. Acetate=1): = < 1

• Stability: Product is stable under normal conditions.
• Hazardous Decomposition Products: Carbon monixide and ioxide on combustion
• Hazardous Polymerization: will not occur.
• Incompatibility: Strong oxidizers. May soften some plastics.
• Conditions to Avoid: Incompatibilites.

• Toxicological Data:
• RTECS: CAS# 64742-94-5: 1002713AH / CAS# 91-20-3 QJ0525000 / CAS# 67-63-0: NT8050000 /CAS# 102-71-6: KL9275000 / CAS# 577-11-7 WN0525000 / CAS# 111-76-2: KJ8575000 / CAS# 112-34-5: KJ9100000 / CAS#128-37-0:GO7875000

LD50 /LC50: CAS# 64742-94-5: Inhalation, rat LD50 = 590 mg/m3/4H / CAS# 91-20-3: Acute oral, rat LD50 = 490 mg/kg; acute dermal, rat = 2.5 g/kg; acute dermal, rabbit = 20 g/kg / CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit = 12800 mg/kg / CAS# 102-71-6: Oral, mouse: LD50 = 5846 mg/Kg; Oral, rabbit: 2200 mg/Kg; Oral, rat: LD50 = 4920 mg/Kg; Skin, rabbit > 20 ml/Kg; Skin, rat > 16 ml/Kg / CAS# 577-11-7: Oral, mouse: LD50 = 2643 mg/Kg; Oral, rat: LD50 = 1900 mg/Kg; Draize skin, rabbit = 10 mg in 24 hrs, moderate / CAS# 111-76-2: Inhalation, mouse: LC50 =700 ppm/7H; Inhalation, rat: LC50 =450 ppm/4H; Oral, mouse: LD50 = 1230 mg/kg; Oral, rabbit: LD50 = 300 mg/Kg; Oral, rat: LD50 = 470 mg/Kg; Skin, rabbit: = 220 mg/Kg / CAS# 112-34-5: Oral, mouse: LD50 = 6050 mg/Kg; Oral, rabbit: 2200 mg/Kg; Oral, rat: LD50 = 5660 mg/Kg /CAS# 128-37-0: Oral, mouse LD50=1,040 mg/Kg, Oral, rat LD50=890 mg/Kg

• Carcinogenicity:

ACGIH-A4 - Naphthalene, CAS# 91-20-3 "suspected animal carcinogen

IARC Group 3 - Butylated hydroxytoluene (BHT),CAS #128-37-0, Triethanolamine, CAS#102-71-6, Isopropyl alcohol, CAS# 67-63-0 are listed as "Confirmed Animal Carcinogens" Naphthalene, BHT, Triethanolamine & Isopropyl alcohol are NOT present on NIOSH, NTR or OSHA carcinogenicity lists

Other Ingredients not listed by ACGIH, IARC, NIOSH, NTR, or OSHA

• Environmental Fate: NDA
• Environmental Toxicity:

CAS# 111-76-2: 24-Hr. LC50; goldfish: 1650 mg/L 96-Hr. LC50; bluegill sunfish: 1490 mg/L 96-Hr. LC50; tidewater silversides: 1250 mg/L
CAS# 67-63-0: 24 hr. LC50 aquatic effects: Fathead minnow: LC50 =1000 mg/L/96 Hr. Golden orfe: LC50 = 8970 mg/L/48 Hr. goldfish: LC50 = GT5000 mg/L/24 Hr.
CAS#102-71-6: LC50=Fathead minnow 5600 mg/L/96 hour

• Biodegradability: All ingredients are easily biodegraded by Alken-Clear-Flo 7008 and 7036. No food chain concentration potential for any ingredients.

• DOT Proper Shipping Name: Not regulated as hazardous by DOT when packaged in drums of 148 gallons or less.
  ----------------------------------------------------------------------------------------------------------------------
  Packages of above 148 gallons each:
• DOT Proper Shipping Name: Environmentally Hazardous Substance, Liquid N.O.S (Contains Methylnaphthalene, liquid, naphthalene and Trimethylbenzene, liquids)
• DOT Hazard Class: 9
• UN: 3082
• Packing Group: III
• DOT Label: Environmentally Hazardous Substance, Liquid, N.O.S (Contains Methylnaphthalene, liquid, naphthalene and Trimethylbenzene) 9, UN 3082, III Marine Pollutant
  

• TSCA: (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA. CAS 64742-94-5 is listed as a UVCB (Unknown, variable composition) Chemical.
• CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302
• SARA TITLE III:

..................................Section 302/304 Extremely Hazardous Substances: None

................................. Section 311 Hazard Categorization: Acute health, chronic, delayed Health, Fire

..................................Section 313 Toxic Chemicals: None

• STATE RIGHT-TO-KNOW lists: 2-Butoxyethanol, CAS#111-76-2 (< 1%)can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. Naphthalene, CAS# 91-20-3, (11%) is listed on California, Connecticut, Florida, Illinois, Louisiana, Massachusetts, Maine, Minnesota, New Jersey, Pennsylvania, and Rhode Island right to know lists. Isopropyl alcohol, CAS# 67-63-0 (< 2%) is listed on the following RTK lists: California, New Jersey, Florida, Pennsylvania, Minnesota & Massachusetts. Butylated hydroxytoluene, CAS# 128-37-0 (< 1%) is found on the following RTK lists: California, New Jersey, Pennsylvania, Minnesota & Massachusetts. Triethanolamine, CAS# 102-71-6, (<2%) is found on the following RTK lists: Massachusetts, Minnesota, Pennsylvania, and Rhode Island .Other ingredients are NOT listed on any of the following state right to know lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Maryland, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island or Tennessee.
• CALIFORNIA PROPOSITION 65 LABELING: This product contains the following chemical(s) known to the state of California to cause cancer and/or birth defects and/or reproductive harm: 11% Naphthalene, CAS#91-20-3, < 1% Butylated hydroxytoluene (BHT), CAS# 128-37-0 and 2% Triethanolamine, CAS# 102-71-6.
• CARB: Product meets the low vapor pressure (LVP) exemption set by the California Air Resources Board for volatile organic compounds in consumer products (California Code of Regulations, Title 17, Article 2, Section 94510)
• CLEAN WATER ACT/OIL POLLUTION ACT: This product is classified as an oil under Section 31 of the Water Act (40 CFR 110) and the Oil Pollution Act of 1990. Discharges or spills which produce a visible sheen on either surface water or waterways/sewers which lead to surface water, must be reported to the National Response Center at 800-424-8802.
• Canadian DSL: Ingredients are listed on Canada's DSL List. This product is authorized for sale in Canada.
• Canada's Ingredient Disclosure List. Naphthalene, CAS# 91-20-3, 11% of product and Triethanolamine, CAS# 102-71-6, representing 2% of product, ARE listed on the Canadian CIDL. Other Ingredients are not listed on the CIDL. This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
• Federal Export Regulations: Schedule B/IHTS 3811.90.0000 Prepared additives for mineral oil NESOI, ECCN: 1C350 Schedule 3 Triethanolamine, CAS# 102-71-6,NLR due to concentration of < 2% (exempt below 30%)
  

16. Other Information

Reason for Revision: Routine Review & Revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.