ALKEN CLEAR-FLO® 7036

Effective Date: 03/19/2007

 Product Bulletin


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 Material Safety Data Sheet
 Manufacturer's Name: Alken-Murray Corporation
 Manufacturer's Address: P.O. Box 400, New Hyde Park, New York 11040
  T: 540-636-1236 Fax: 540-636-1770
  E-mail: msds@alken-murray.com 
 Manufacturer's Cage Code: 2A384
For chemical emergency - spill, leak, fire or accident - call CHEMTREC - day or night - (800) 424-9300 or outside the USA (703) 527-3887

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NFPA Hazard Ratings:

0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe


 Health=1  Fire=1  Reactivity=0

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1. Product Identification

 Synonyms:  Broad-Spectrum Petroleum Hydrocarbon Degrader
 CAS Number:  Not applicable to mixtures
 Chemical Formula:  Mixture
 Formula ID Codes: 7036

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2. Composition/Information on Ingredients

*Natural dolomitic limestone contains a variable composition, which usually includes 0.1 to 1 % crystalline silica (quartz), which is why this "ingredient" is listed on this MSDS

Ingredients not precisely identified are proprietary and/or non-hazardous per 29 CFR 1910-1200 and/or represent less than 1%. All chemical ingredients appear on the EPA TSCA inventory

 Chemical Name  CAS Number  OSHA PEL  ACGIH TLV   % Weight
 Wheat bran  116469-86-4   NDA   NDA  75 - 85
 Water   7732-18-5   NDA   NDA   10 - 15
 *Dolomitic limestone (calcium carbonate, magnesium carbonate and ferric oxide)   1317-65-3  0.05 mg/M3  15 mg/M3  5 - 10
 Viable bacterial cultures  NA  NDA   NDA   1
 *Crystalline silica (quartz)  14808-60-7   0.05 mg/M3   0.05 mg/M3     < 0.1

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3. Hazards Identification

Emergency Overview: This product contains five (5) strains of Pseudomonas aeruginosa, a species rated BioSafety Class 2 by the Centers for Disease Control, but these five strains have been tested deficient for Toxin-A production, making them as safe as species identified as BioSafety Class 1, like the other fifteen (15) strains in this formula. BioSafety Class 1 microorganisms are defined by the Centers for Disease Control to be unlilkely to cause disease in healthy humans or animals. However, persons with compromised immune systems should avoid contact with open wounds and/or breathing dust or mist from manufacturing processes. These organisms are susceptible to many commonly used antibiotics, and Alken-Murray is willing to supply antibiotic sensitivity information to any doctor or import health authority requesting it. Although bacterial cultures included in this product were grown in a sterile aqueous medium
containing a variety of nutrients, including corn syrup solids, digests of soybean and/or skim milk, glucose or other sugars, vegetable oils, including olive oil, yeast extract, mineral salts, etc., the concentrations of these residual nutrients are believed to be below levels capable of triggering irritation or allergic reactions.

Copies of original supporting Toxin-A deficiency testing and related papers plus our "Confidential Specifications Sheet for CF 7036" (includes antibiotic sensitivity, morphology and enzyme profiles for strains in the formula) are available to any health authority, medical doctor or authorized distributor, once they sign and return a copy of our "trade secret agreement".


Access the antibiotic sensitivity chart at http://www.alken-murray.com/antibio-strain.pdf , which provides results of Kirby-Bauer antibiotic sensitivity screening of Alken-Murray's bacterial strains, on a strain by strain basis. See more about Alken-Murray's policies in that document.

Potential Health Effects:

  • Signs and Symptoms of Acute Overexposure: Eye, skin irritation
  • Signs and Symptoms of Chronic overexposure: Dermatitis and skin sensitization
  • Medical Conditions Generally Aggravated by Exposure: Allergies, dermatitis.
  • Ingestion: No effect if ingested in small amounts. Relative to other materials, a single dose of this product is rarely toxic by ingestion. Irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion.

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4. First Aid Measures

  • Inhalation: Remove victim to fresh air
  • Ingestion: Give victim water or milk to drink to dilute the product. Get medical advice..
  • Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
  • Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
  • Note to Physician: If patient's immune system is compromised, request antibiotic sensitivity chart from Alken-Murray Corporation by e-mail: clearflo@shentel.net

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5. Fire Fighting Measures

 Flash Point: NA

Flammability Limits: NA

Autoignition temp: NA

Fire Extinguishing Media: Water spray, carbon dioxide, dry chemical

Special Fire-Fighting Information: None

Unusual Fire and Explosion Hazards: None

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6. Accidental Release Measures

For small spills, flush to waste treatment sewer (product is biodegradable). For large spills, contain and collect for reuse. Wear approved respirator for nuisance dust during cleanup.

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7. Handling and Storage

 Store in cool dry place. Keep container closed when not in use. Avoid storage of product above 110 degrees F and keep from freezing. Keep out of direct sunlight.

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8. Exposure Controls/ Personal Protection

  • Ventilation System: Good general ventilation is advisable
  • Personal Respirators (NIOSH Approved): if needed, use respirator to screen out nuisance dust
  • Skin Protection: Long sleeved clothing
  • Eye Protection: Safety glasses if dust is raised
  • Other Control Measures: Minimize exposure in accordance with good hygiene practice. Avoid handling which would create large amounts of dust.

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9. Physical and Chemical Properties

  • Appearance and Color: Free-flowing tan to brown powder.
  • Odor: Yeast-like odor
  • Solubility in Water: Moderate, contains viable bacteria
  • Specific Gravity: NDA
  • Bulk density: Approximately 0.66-0.77 gm/cm3
  • pH: 6.5-8.5
  • % volatile by volume @ 21C (70F): Nil
  • Boiling Point: NA
  • Melting Point: NA
  • Vapor Density (Air=1): NA
  • Vapor Pressure (mm Hg): NA
  • Evaporation Rate (Bu. Acetate=1): NA

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10. Stability and Reactivity

  • Stability: Product is stable.
  • Hazardous Decomposition Products: None
  • Hazardous Polymerization: will not occur.
  • Incompatibility: Acids, alkalies, other toxic materials may inactivate biological cultures.
  • Conditions to Avoid: Incompatible substances

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11. Toxicological Information

  • Toxicological Data: (CFR Title 16)
RTECS: Bacterial cultures: 1004274VB / CAS 116469-86-4: 1012301CS/ CAS 7732-18-5: ZC0110000/ CAS# 1317-65-3: EV9580000/ CAS# 68920-42-3: NDA / CAS# 14808-60-7:VV7330000
 
LC50/LD50: CAS# 116469-86-4: this is a natural food substance with no reported ingestion toxicity / CAS# 7732-18-5: LD50= >90 mL/Kg / CAS# 1317-65-3: Oral, rat LD50 = 6450 mg/Kg / CAS# 68920-42-3: NDA / CAS# 1408-60-7: Oral, rat LD59 = 500 mg/Kg
  • Carcinogenicity:
NTP - Crystalline silica, CAS# 14808-60-8 - "Human Carcinogen" List,
ACGIH-A2 -
Crystalline silica, CAS# 14808-60-8 "Suspected Human Carcinogen" List
IARC-Group 1 -
Crystalline silica, CAS# 14808-60-8, "ProvenHuman Carcinogen" List
Other ingredients are NOT found on any lists published by ACGIH, IARC, NIOSH, NTP or OSHA

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12. Ecological Information

 Environmental Fate: This product is not likely to bioconcentrate and is unlikely to create any negative environmental impact, other than a slight reduction in oxygen concentration at the site of release. : If very high concentrations are released into a waterbody, oxygen levels may decrease in the immediate area

Environmental Toxicity: NDA

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13. Disposal Considerations

 RCRA Hazard Class (if discarded): Neat, unused product is not considered a hazardous waste, according to RCRA regulations 40 CFR 261. For proper disposal of used materials, an assessment must be completed to determine the proper waste management options permissible under applicable rules, regulations and/or laws governing client's location. Wash containers down with water and disinfect with a 1% sodium hypochlorite solution before disposal Then remove or deface product label to avoid confusion if pail or drum is later refilled. Clean, empty containers should be recycled or disposed of through an approved waste management facility.

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14. Transportation Information (49 CFR 172.101)

  • DOT Proper Shipping Name: Not regulated as hazardous by DOT
  • DOT Hazard Class: None
  • DOT Label: Class 60 (item 20400) "Bacteria, sewage or industrial waste treating, in dry or liquid carrier, with or without enzymes in bulk, bags, barrels or pails." Alken Clear-Flo® 7036

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15. Regulatory Information

 
  • TSCA:  (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
  • CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302
  • SARA TITLE III:

..................................Section 302/304 Extremely Hazardous Substances: None

..................................Section 311 Hazard Categorization: Acute, chronic

..................................Section 313 Toxic Chemicals: None

  • Clean Air Act: This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
  • Clean Water Act: This product contains no ingredients that CWA lists on its "Hazardous Substances", "Priority Pollutant" or "Toxic Pollutant" lists.
  • OSHA: None of the ingredients are considered Extremely Hazardous by OSHA.
  • STATE RIGHT-TO-KNOW LAWS:Limestone (CAS# 1317-65-3), 9% of product IS listed on the Massachusetts, Minnesota, New Jersey and Rhode Island RTK lists. Crystalline silica (CAS#14808-60-7), <0.1% of product is listed on the California, New Jersey, Pennsylvania, Minnesota & Massachusetts RTK lists. Other ingredients are not listed on any of the following state right to know lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Rhode Island or Tennessee.
  • California Proposition 65 Labeling required for this surfactant: This product contains <0.1% Crystalline Silica (CAS# 14808-60-7), a chemical known to the state of California to cause cancer and/or birth defects or reproductive harm.
  • Canadian DSL: This product contains thirteen (13) strains of bacteria that are NOT listed on the currently published Canadian DSL. We advise Canadian clients to discuss with Alken-Murray's authorized Canadian distributor, Dave Pawlowski, obtaining a LIMITED IMPORT EXEMPTION for non-DSL bacterial cultures, since Alken-Murray Corp. Is unable to formulate a microbial formula that effectively targets the same pollutants that this product targets, while remaining in compliance with the Canadian DSL list. 
  • Canada's Ingredient Disclosure List: Crystalline silica (CAS#14808-60-7, <0.1% is listed on the CIDL Ingredients are not listed on the CIDL.This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
  • IHT Code: 3002.90.5150 "Microbial cultures for Environmental Defense, Bioremediation"

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16. Other Information

Reason for Revision: Routine review and revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.

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E-mail: indusmuni@alken-murray.com

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