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19. Why is the discharge of BOD & COD regulated?

Definition: BOD = Biochemical Oxygen Demand - The rate at which microorganisms use the oxygen in water or wastewater, while stabilizing decomposable organic matter under aerobic conditions. In decomposition, organic matter serves as food for the bacteria and energy results from its oxidation. The BOD test procedure measures the rate of oxygen use under controlled conditions, usually incubation in the dark at 20°C for 5 days.

EPA regulation 40CFR Part 503 contains rules for disposal of treated biosolids as fertilizer. The 180 page EPA Publication 832-R-93-003, Plain English Guide to EPA 503 Biosolids Rule, explains the regulations governing recycling of treated sludge and other biosolids through anaerobic and aerobic digestion processes, heat treatments etc. The EPA also issues discharge permits that specify the limits of chemicals, nutrients, and bacteria that may be safely discharged to the environment.
The above mentioned rules are not arbitrary. The discharge of pathogenic bacteria and excess nutrients in high BOD must be controlled to protect the ecology. Depositing large quantities of undigested nutrients onto the land upsets the balance of the nitrogen cycle. High BOD waste kills certain plants, leads to the growth of different plants on land leading to starvation for the indigenous populations of animals, birds, and insects. Leachate from land applications of this waste can pollute the water table and nearby rivers and lakes, where these excess nutrients support different phytoplankton which cannot be digested by the normal populations of fish, oysters, and shrimp, leading to massive death of aquatic life, which leads to death of the predators that feed on these species. Other hazards of depositing high BOD waste into rivers include: the proliferation of pathogenic species of bacteria, the proliferation of Pfiesteria (a microorganism which has caused so much fish damage that entire rivers have been closed during certain seasons), and massive fish kills due to insufficient oxygen in the water as the high BOD waste uses up the oxygen that is present. The odors from high BOD waste attract pest and scavenger birds, insects, fish and animals, thus allowing these populations to increase at the expense of other species.
High COD waste containing chemicals, such as arsenic, cadmium, chromium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc can poison the natural population of (unselected, unadapted) waste degrading bacteria, thereby breaking the food chain and leading to all the problems associated with a high BOD waste mentioned in the previous paragraph. High levels of these chemicals can also directly poison higher life forms. Permits are established limiting the amount of these toxins released to the environment in a given location.
Biosolids produced from a municipal facility or one that processes restaurant and animal farm waste should be sampled and tested monthly for the following pathogens to meet the specifications of this rule: fecal coliform, salmonella sp., enteric virus, viable helminth ova, inorganic pollutants, specific oxygen uptake (BOD/COD) and total fixed and volatile solids.

 

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