Signs and Symptoms of
Acute Overexposure: Eye,
skin irritation. Inhalation of heated vapors may irritate the respiratory
Signs and Symptoms of
Chronic overexposure: Prolonged
inhalation of concentrated.heated vapors may cause damage to the kidneys.
Reddening and swelling of affected area with possile itching, burning or
Medical Conditions Generally
Aggravated by Exposure:
Existing cuts, rashes, allergies, or other sensitive areas.
Ingestion: Ingestion may result in abdominal pain,
nausea, and vomiting.
4. First Aid Measures
Inhalation: Remove victim to fresh air
Ingestion: Give victim water or milk to drink to dilute
the product. Get medical advice..
Skin Contact: Remove contaminated clothing and footwear.
Wash skin with soap and water. Wash clothing before reuse.
Eye Contact: Immediately flush eyes with water for
15 minutes. Get medical attention.
Note to Physician: None
5. Fire Fighting Measures
Flash Point: > 212 degrees F (PMCC)
Flammability Limits: NDA
Autoignition temp: NDA
Fire Extinguishing Media:
Carbon dioxide, dry
chemical, Halon 1211, water
Special Fire-Fighting Information:
Spilled chemical creates
extremely slippery conditions, especially in contact with water. Use caution.
Respiratory and eye protection are reqyired. Petroleum component is combustible,
if separated from other ingredients. Vapors/fumes will ignite.
Unusual Fire and Explosion
6. Accidental Release Measures
Contain and collect, using a suitable
absorbent if needed (sand, earth or vermiculite). Flush residuals to drain
with water for normal biological water treatment. Place collected material
into suitable containers for disposal. Can usually be disposed of my approved
metered release to WWTP or other approved disposal. Observe local, federal
and state disposal regulations. Several washes and/or the use of detergents
may be necessary to completely clean any spills.
7. Handling and Storage
Handle as an irritant. Do not
get in eyes. Avoid prolonged/repeated skin contact. Do not inhale vapors/mists.
Do not ingest. Store away from sources of ignition. Spilled product creates
very slippery condition, especially in contact with water.
8. Exposure Controls/ Personal Protection
Ventilation System: Good general ventilation is advisable.
Local exhaust desired.
Personal Respirators (NIOSH
Approved): None required
for normal use and processes. if needed, use respirator to filter out mists/vapors.
Skin Protection: Long sleeved clothing, impervious rubber
or neoprene gloves and protective apron.
Eye Protection: Safety glasses or goggles
Other Control Measures:
in accordance with good hygiene practice. Avoid handling which would create
large amounts of mists/vapors. Exxon Medical Research recommended inhalation
TLV for CAS 64742-47-8 of 200 ppm.
9. Physical and Chemical Properties
Appearance and Color:
Odor: Mild amine-like
Solubility in Water: Soluble to a maximum concentration of 1%
RTECS: CAS# 69418-26-4:AS3700000/ CAS#64742-47-8: CA5504000/
CAS 9002-92-0:JR5960000, JR5970000, MD0875000
Potential Eye Effects: A primary eye irritation study in rabbits
was conducted (using EPA guidelines No. 81-4) using a test material similar
to that represented by this MSDS. The results indicated the test material
was rated as moderately irritating. "Positive corneal involvement
persisted through day 21; therefore the test material was assigned to Toxicity
Category I. Potential Effects of Skin Contact: A primary dermal irritation study
in rabbits was conducted (using EPA guidelines No. 81-5) using a test material
similar to that represented by this MSDS Test results indicated a primary
irritation index of 4.1 out of a possible 8.0, or a descriptive rating
of moderately irritating. Based on 72 hour score only, the test material
was assigned to Toxicity Category II (severe irritation). This product
contains a surfactant which may result in the development of inflammatory
changes in the lung, based on studies with rabbits, in which the undiluted
surfactant was kept in sustained, occluded contact with the rabbit's skin.
See specific LD50 information below for the surfactant in question, which
is present below 3% of polymer formula. LD50 /LC50: CAS# 9002-92-0:Oral, rat LD50 = 1,000 mg/Kg, Oral, mouse
LD50 = 1170 mg/Kg; CAS#69418-26-4: Oral,rat LD50 = 5,000 mg/Kg, Dermal
rabbit, non-irritating even at high dosages.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTR,
12. Ecological Information
Environmental Fate: The product is rapidly eliminated from
the aquatic medium through irreversible adsorption onto suspended matter
and dissolved organics
Environmental Toxicity: Ingredients are toxic to fish, unless
adsorbed onto humic or organic matter.
13. Disposal Considerations
RCRA Hazard Class (if
unused product is not considered a hazardous waste, according to RCRA regulations
40 CFR 261. . For proper disposal of used materials, an assessment must
be completed to determine the proper waste management options permissible
under applicable rules, regulations and/or laws governing client's location.
Use until less than 1 inch remains in the container, triple rinse with
clean water, and pour rinse water to sewer. Then remove or deface product
label to avoid confusion if pail or drum is later refilled. Clean, empty
containers should be recycled or disposed of through an approved waste management
14. Transportation Information
DOT Proper Shipping Name: Not regulated as hazardous by DOT or Canadian
DOT Hazard Class: None
DOT Label: Class 60:(NMFC
item #4612, LTL) "adhesives, adjuvents, spreaders, sliders, liquid,
in pails or drums" Alken Solutions C111K, cationic polyquaternary
15. Regulatory Information
TSCA: : (40CFR 710) All chemical ingredients
are listed on the TSCA 8(b) inventory. None of the ingredients are on the
Health and Safety Reporting List, are under Chemical Test rule, are listed
under TSCA Section 12B, or have a SNUR under TSCA CERCLA Reportable Quantity: This product does NOT contain
ingredients that have Reportable Quantity (RQ) requirements under US 40
Clean Water Act: This product is considered an oil under
Section 311 of the Clean Water Act (40 CFR 110) and the Oil Pollution Act
of 1990. Discharges that produce a visible sheen on surface waters or on
waterways or sewers that lead to surface water must be reported to the
National Response Center, 800-424-8802. Product can be bioremediated with
Alken Clear-Flo 7008.
Clean Air Act : Ingredients not listed as hazardous pollutants
under CAA. This product does not contain any Class 1 or Class 2 ozone depletors,
nor was it made with such chemicals.
OSHA: None of the ingredients are considered Extremely
Hazardous by OSHA.
STATE RIGHT-TO-KNOW LAWS:. Ingredients not listed on California,
Connecticut, Florida, Illinois, Louisiana, Massachusetts, New Jersey, New
York, Pennsylvania, or Rhode Island.
Not subject to California Proposition
65 labeling requirements
Canadian WHMIS Classification:
CAS 64742-47-8: B3. Combustible
Liquid, but flash point of formulated product has a flash pint above flammable-combustible
limit for Canada
Canadian DSL: all ingredients listed and compliant
Canada's Ingredient Disclosure
List:Light hydrotreated kerosine solvent CAS#
64742-47-8, comprising 25% of this product IS listed on the CIDL, but other ingredients are "NOT CONTROLLED".
This MSDS has been prepared according to the hazard criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all of the information
required by the CPR.
TDG Classification: Not regulated as hazardous by Canadian
IHT Codes: 3906.90.5000
16. Other Information
Reason for Revision: Changed fax and e-mail
provides the information contained herein in good faith, in compliance with
the Occupational Safety and Health Act of 1970, but makes no representation
as to its comprehensiveness or accuracy. This document is intended only
as a guide to the appropriate precautionary handling of the material by
a properly trained person using this product. Alken-Murray warrants that
this product is of merchantable quality. The implied warranty of fitness
for a particular purpose is limited to the extent the products are used
for the purpose or uses described on the product's label or in any written
instructions or materials distributed to the buyer by Alken-Murray and is
hereby disclaimed should buyer use the products in a manner inconsistent
with this uses or purposes described therein. In no event shall Alken-Murray
be liable for any consequential, exemplary, or incidental damages incurred
by buyer even if it has been advised of the possibility of such damages.